A Restudy of Direct Chelatometric Titration of Vanadium(IV) with N-Benzoyl-N-phenylhydroxylamine as Indicator

This paper restudies the method of direct chelatometric titration of V(IV) with N-benzoyl-N-phenylhydroxylamine (BPHA) as indicator. The indicator functions entirely differently from indicators hitherto used in chelatometry. The solution contains two independent systems – the indicator and the titrand-titrant system – without any color changing species. The BPHA-V(V) chelate once formed as the result of aerial oxidation constitutes the indicator system and does not react with EDTA. Its color therefore remains unchanged throughout titration. It is not a metallochromic indicator. Its function is that of color-screening. The color of the titrant system deepens during titration, but does not change. The end-point is indicated by one color completely covering up the other. Hence, this method is of purely empirical nature.Received July 5, 2002; accepted February 11, 2003 Published online July 16, 2003     

Inter- and intramolecular non-covalent interactions in 1-methylimidazole-2-carbaldehyde complexes of copper,silver, and gold

Three new imidazole compounds, [CuBr₂(mimc)₂] (1), [Ag(mimc)₂][CF₃SO₃] (2), and [AuCl₃(mimc)] (3) (mimc = 1-methylimidazole-2-carbaldehyde), have been synthesized, structurally characterized, and further analyzed using the QTAIM analysis. The compounds exhibit self-assembled 3D networks arising from intermolecular non-covalent interactions such as metallophilic interactions, metal-π contacts, halogens–halogen interactions, and hydrogen bonds. These weak interactions have a strong impact on the coordination sphere of the metal atoms and on the packing of compounds 1, 2, and 3.     

离子对UIO-66-2OH光催化性能的影响

实际废水中存在的离子会对有机污染物的光催化降解产生影响。以ZrCl₄和2,5-二羟基对苯二甲酸为原料,通过水热合成法成功制备了金属有机骨架材料UIO-66-2OH。通过红外（IR）、X射线粉末衍射（XRD）、X射线光电子能谱（XPS）和扫描电子显微镜（SEM）对UIO-66-2OH的结构进行表征。利用水中常见的金属阳离子和无机阴离子,探索UIO-66-2OH的光催化性能。研究发现,金属阳离子Fe³⁺和无机阴离子HCO₃^-、CO₃^2-可以加快光催化降解的速度。然而,金属离子Na⁺、K⁺、Ca²⁺、Mg²⁺、Cu²⁺和无机阴离子Cl^-、SO₄^2-、PO₄^3-会抑制光催化性能,且离子价态越高,抑制效果越明显。     

OFDM水声通信CS限幅失真补偿与LS信道估计优化算法*

正交频分复用技术应用于水声通信系统时,会引起较高的峰均比,当采用限幅法对峰均比进行抑制时,会产生非线性失真。另外,系统采用最小二乘法进行信道估计受噪声的影响较大。针对以上问题,提出了一种基于压缩感知技术的补偿限幅非线性失真与最小二乘信道估计相组合的新算法,在接收端利用导频数据采用压缩感知算法对限幅失真进行补偿,同时对最小二乘信道估计进行优化运算,以减小噪声对其影响。理论分析和仿真结果均表明,新算法不但能够有效抑制限幅法造成的系统非线性失真问题,而且能够降低高斯白噪声对于信道估计的影响。     

Oscillation of Third-order Delay Dynamic Equations on Time Scales

This paper is concerned with the oscillatory behavior of a class of third-order noonlinear variable delay neutral functional dynamic equations on time scale. By using the generalized Riccati transformation and inequality technique, we establish some new oscilla- tion criteria for the equations. Our results extend and improve some known results, but also unify the oscillation of third-order nonlinear variable delay functional differential equations and functional difference equations with a nonlinear neutral term. Some examples are given to illustrate the importance of our results.     

时间测度链上具正负系数的二阶阻尼动力方程的振动准则

研究了时间测度链上一类具正负系数和阻尼项及非线性中立项的二阶变时滞非线性动力方程的振荡性.利用时间测度链上的有关理论及广义Riccati变换,结合大量不等式技巧,建立了该方程若干新的振动准则,这些准则不仅推广和改进了一些已知的结果,而且在时间测度链上统一了二阶非线性时滞阻尼微分方程和二阶非线性时滞阻尼差分方程的振动性质.     

Exponential stability of impulsive high-order cellular neural networks with time-varying delays

The paper considers the problems of global exponential stability for impulsive high-order neural networks with time-varying delays. By employing the Hardy inequality and the Lyapunov functional method, we present some new criteria ensuring exponential stability. The activation functions are not assumed to be differentiable or strictly increasing, and no assumption on the symmetry of the connection matrices is necessary. These criteria are important in signal processing and the design of networks. Moreover, we also extend the previously known results. One illustrative example is also given in the end of this paper to show the effectiveness of our results.     

电解铜箔表面电沉积Zn-Ni-P-La合金工艺

为了缓解我国高性能铜箔依靠进口的局面,进行了将类金属(P)和稀土金属(La)引入电解铜箔锌镍合金镀层中以获得高耐腐蚀性铜箔的实验。 利用电子能谱(XPS)、X射线衍射(XRD)、扫描电子显微镜(SEM)等技术手段分析镀层质量。 在最佳工艺下获得非晶态Zn-Ni-P-La合金镀层,镀层表面平整均匀、结晶致密,未钝化的情况下,铜箔镀件在180 ℃烘箱中保持1 h不变色,表现出较理想的抗氧化和抗腐蚀能力。 表明镀层中适量的P和稀土La对改善镀层质量有着重要的作用,具有较好的工业应用前景。     

非自治动力系统中周期跟踪和极限跟踪的研究

根据自治动力系统中周期跟踪性和极限跟踪性的定义,将其引入到非自治动力系统。研究了非自治动力系统中周期跟踪性和极限跟踪性的动力学性质,得到：(1)若F={fi}i=0∞拓扑共轭于G={gi}i=0∞,则F具有周期跟踪性当且仅当G具有周期跟踪性;(2)若F={fi}i=0∞拓扑共轭于G={gi}i=0∞,则F具有极限跟踪性当且仅当G具有极限跟踪性;(3)若乘积系统(X×Y,F×G)具有周期跟踪性,则(X,F)和(Y,G)具有周期跟踪性。 以上结论对非自治动力系统中跟踪性的发展有一定的促进作用。     

一类非线性差分系统边值问题解的存在性

本文应用临界点理论建立了一类非线性差分系统边值问题解的存在性定理,所得结论推广了相关文献的结果.